Alicia Keys and the White Stripes' Jack White will record the theme song to "Quantum of Solace," the 22nd James Bond film, which hits U.S. theaters Nov. 7.

The song, "Another Way To Die," will be the first duet in Bond soundtrack history. White wrote and produced the song, and also will play drums. The soundtrack to the movie will be released Oct. 28.

The score for the film will be composed by David Arnold.

"Quantum of Solace," starring Daniel Craig, will be directed by Marc Forster from a screenplay by Neal Purvis & Robert Wade and Paul Haggis.

Amy Winehouse and Leona Lewis had previously been rumored as the vocalists for the latest Bond theme.

Jack White and Alicia Keys?? What an odd combination! I love the White Stripes' style plus I suppose Alicia can bring a blues-y feel to it, I'm so interested to hear the song... I hope they do a good job!

Completely odd combination, but with White predominantly behind it I can't wait to hear a few bars :)

Keys already did a bluesy song with John Mayer on her last album, it'll be interesting to see how this one turns out